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By John R. Weeks, Hugh S. Isaacs (auth.), Mars G. Fontana, Roger W. Staehle (eds.)

ISBN-10: 146158258X

ISBN-13: 9781461582588

ISBN-10: 1461582601

ISBN-13: 9781461582601

This sequence was once geared up to supply a discussion board for overview papers within the region of corrosion. the purpose of those reports is to carry definite components of corrosion technological know-how and expertise right into a sharp concentration. The volumes of this sequence are released nearly on a each year foundation and every includes 3 to 5 stories. The articles in every one quantity are sekcted in this kind of means as to be of curiosity either to the corrosion scientists and the corrosion technologists. there's, in reality, a specific target in juxtaposing those pursuits as a result significance of mutual interplay and interdisciplinarity so very important in corrosion reports. it truly is was hoping that the corrosion scientists during this method may well remain abreast of the actions in corrosion know-how and vice versa. during this sequence the time period "corrosion" is utilized in its very broadest feel. It comprises, accordingly, not just the degradation of metals in aqueous en­ vironment but additionally what's as a rule known as "high-temperature oxidation. " additional, the plan is to be much more common than those subject matters; the sequence will contain all solids and all environments. this present day, engineering solids contain not just metals yet glasses, ionic solids, polymeric solids, and composites of those. Environments of curiosity needs to be prolonged to liquid metals, a wide selection of gases, nonaqueous electrolytes, and different non­ aqueous liquids.

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_ - _ . . . . . . . . . . . . _ -. . . • • • u ! : - = :I) ___ .... _ C ~ UJ 0:: 1000 ~ 1200 a. C 01 I ,i ( --... a. ______________________ -.. •.... '........ 'i UJ D.. -200 I- ~-100 Uj '" u '"~z: ffi 4 I- D.. 0 0 John R. Weeks and Hugh S. 0 1: o :g..... 0 '" E . =80 t- D ;;= TYJ T, "C 720 710 ~2~~6~~IO~~14~-±18~~~±-~2~6-L~~~~~~700 DISTANCE •INCHES Fig. 19. 4 ppm oxygen. " tions of Cr and Ni with L/ D in this isothermal region. During this same rlln the corrosion rate decreased by a factor of",-, 2i in going from L/D = 200 to L/D = 600.

Corrosion of the intermediate alloys lies between these extremes, but gradually shifts with time toward the behavior of steels as the a layer forms. This is attributed to an effect on the kinetics of Fe dissolution rather than of Cr dissolution. 5 power up to a critical velocity, above which corrosion becomes independent of velocity. The effect on the corrosion of stainless steels of varying mass flow at constant Reynolds number is negligible at zero downstream, but becomes increasingly significant with increasing downstream position.

Isaacs nsmg-temperature region. In the first case, the required size of the particulates approaches the atomic diameter of Fe, so that they are therefore no longer particles, and in the second case, the sodium must contain several per cent iron as l-fLm particles, which is easily shown to be false by Fe analysis of Na from operating systems. , 10-1000 times faster, although, since they move with the Na, the reverse is more likely to be the case in high-velocity systems. It was decided to incorporate a "fudge factor" into the calculation to vary the contribution from the particulates by varying the ratio of their corrosion rate to that of the steel wall.

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Advances in Corrosion Science and Technology by John R. Weeks, Hugh S. Isaacs (auth.), Mars G. Fontana, Roger W. Staehle (eds.)

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